Nickel-catalyzed cross-coupling of photoredox-generated radicals: uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings O Gutierrez, JC Tellis, DN Primer, GA Molander, MC Kozlowski Journal of the American Chemical Society 137 (15), 4896-4899, 2015 | 530 | 2015 |
Redox-neutral photocatalytic cyclopropanation via radical/polar crossover JP Phelan, SB Lang, JS Compton, CB Kelly, R Dykstra, O Gutierrez, ... Journal of the American Chemical Society 140 (25), 8037-8047, 2018 | 205 | 2018 |
On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling … M Yuan, Z Song, SO Badir, GA Molander, O Gutierrez Journal of the American Chemical Society 142 (15), 7225-7234, 2020 | 164 | 2020 |
General method for enantioselective three-component carboarylation of alkenes enabled by visible-light dual photoredox/nickel catalysis L Guo, M Yuan, Y Zhang, F Wang, S Zhu, O Gutierrez, L Chu Journal of the American Chemical Society 142 (48), 20390-20399, 2020 | 140 | 2020 |
Dynamically complex [6+ 4] and [4+ 2] cycloadditions in the biosynthesis of spinosyn A A Patel, Z Chen, Z Yang, O Gutiérrez, H Liu, KN Houk, DA Singleton Journal of the American Chemical Society 138 (11), 3631-3634, 2016 | 136 | 2016 |
Nature of intermediates in organo-SOMO catalysis of α-arylation of aldehydes JM Um, O Gutierrez, F Schoenebeck, KN Houk, DWC MacMillan Journal of the American Chemical Society 132 (17), 6001-6005, 2010 | 134 | 2010 |
A gold-catalysed enantioselective Cope rearrangement of achiral 1, 5-dienes RJ Felix, D Weber, O Gutierrez, DJ Tantillo, MR Gagné Nature chemistry 4 (5), 405-409, 2012 | 127 | 2012 |
Photochemical C–H activation enables nickel-catalyzed olefin dicarbofunctionalization MW Campbell, M Yuan, VC Polites, O Gutierrez, GA Molander Journal of the American Chemical Society 143 (10), 3901-3910, 2021 | 117 | 2021 |
Engaging sulfinate salts via Ni/photoredox dual catalysis enables facile C sp2–SO 2 R coupling MJ Cabrera-Afonso, ZP Lu, CB Kelly, SB Lang, R Dykstra, O Gutierrez, ... Chemical Science 9 (12), 3186-3191, 2018 | 114 | 2018 |
Transition-metal-free chemo-and regioselective vinylation of azaallyls M Li, O Gutierrez, S Berritt, A Pascual-Escudero, A Yeşilçimen, X Yang, ... Nature chemistry 9 (10), 997-1004, 2017 | 85 | 2017 |
Photoredox/nickel‐catalyzed single‐electron Tsuji–Trost reaction: development and mechanistic insights JK Matsui, Á Gutiérrez‐Bonet, M Rotella, R Alam, O Gutierrez, ... Angewandte Chemie International Edition 57 (48), 15847-15851, 2018 | 82 | 2018 |
Mild aromatic palladium-catalyzed protodecarboxylation: Kinetic assessment of the decarboxylative palladation and the protodepalladation steps JS Dickstein, JM Curto, O Gutierrez, CA Mulrooney, MC Kozlowski The Journal of organic chemistry 78 (10), 4744-4761, 2013 | 75 | 2013 |
Stereocontrol in a combined allylic azide rearrangement and intramolecular Schmidt reaction R Liu, O Gutierrez, DJ Tantillo, J Aube Journal of the American Chemical Society 134 (15), 6528-6531, 2012 | 75 | 2012 |
Mechanism of Nakamura’s Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)–C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways W Lee, J Zhou, O Gutierrez Journal of the American Chemical Society 139 (45), 16126-16133, 2017 | 68 | 2017 |
Integrated photocatalytic reduction and oxidation of perfluorooctanoic acid by metal–organic frameworks: key insights into the degradation mechanisms Y Wen, A Rentería-Gómez, GS Day, MF Smith, TH Yan, ROK Ozdemir, ... Journal of the American Chemical Society 144 (26), 11840-11850, 2022 | 62 | 2022 |
Sequential C–H Arylation and Enantioselective Hydrogenation Enables Ideal Asymmetric Entry to the Indenopiperidine Core of an 11β-HSD-1 Inhibitor X Wei, B Qu, X Zeng, J Savoie, KR Fandrick, JN Desrosiers, S Tcyrulnikov, ... Journal of the American Chemical Society 138 (47), 15473-15481, 2016 | 59 | 2016 |
Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity JG Harrison, O Gutierrez, N Jana, TG Driver, DJ Tantillo Journal of the American Chemical Society 138 (2), 487-490, 2016 | 58 | 2016 |
Concerted amidation of activated esters: reaction path and origins of selectivity in the kinetic resolution of cyclic amines via N-heterocyclic carbenes and hydroxamic acid … SE Allen, SY Hsieh, O Gutierrez, JW Bode, MC Kozlowski Journal of the American Chemical Society 136 (33), 11783-11791, 2014 | 55 | 2014 |
Analogies between synthetic and biosynthetic reactions in which [1, 2]-alkyl shifts are combined with other events: dyotropic, Schmidt, and carbocation rearrangements O Gutierrez, DJ Tantillo The Journal of Organic Chemistry 77 (20), 8845-8850, 2012 | 53 | 2012 |
General method for iron-catalyzed multicomponent radical cascades–cross-couplings L Liu, MC Aguilera, W Lee, CR Youshaw, ML Neidig, O Gutierrez Science 374 (6566), 432-439, 2021 | 52 | 2021 |