Matthew Sigman
Matthew Sigman
Professor of chemistry, University of Utah
Verified email at - Homepage
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Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners
R Jana, TP Pathak, MS Sigman
Chemical reviews 111 (3), 1417-1492, 2011
Schiff base catalysts for the asymmetric Strecker reaction identified and optimized from parallel synthetic libraries
MS Sigman, EN Jacobsen
Journal of the American Chemical Society 120 (19), 4901-4902, 1998
A general catalyst for the asymmetric Strecker reaction
MS Sigman, P Vachal, EN Jacobsen
Angewandte Chemie 112 (7), 1336-1338, 2000
Ligand-modulated palladium-catalyzed aerobic alcohol oxidations
MS Sigman, DR Jensen
Accounts of chemical research 39 (3), 221-229, 2006
Recent advances in homogeneous transition metal-catalyzed aerobic alcohol oxidations
MJ Schultz, MS Sigman
Tetrahedron 35 (62), 8227-8241, 2006
Enantioselective addition of hydrogen cyanide to imines catalyzed by a chiral (salen) Al (III) complex
MS Sigman, EN Jacobsen
Journal of the American Chemical Society 120 (21), 5315-5316, 1998
Substrate channelling as an approach to cascade reactions
I Wheeldon, SD Minteer, S Banta, SC Barton, P Atanassov, M Sigman
Nature chemistry 8 (4), 299-309, 2016
Exploiting non-covalent π interactions for catalyst design
AJ Neel, MJ Hilton, MS Sigman, FD Toste
Nature 543 (7647), 637-646, 2017
Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions
KH Jensen, MS Sigman
Organic & biomolecular chemistry 6 (22), 4083-4088, 2008
A Well‐Defined Complex for Palladium‐Catalyzed Aerobic Oxidation of Alcohols: Design, Synthesis, and Mechanistic Considerations
DR Jensen, MJ Schultz, JA Mueller, MS Sigman
Angewandte Chemie International Edition 42 (32), 3810-3813, 2003
Palladium-catalyzed enantioselective oxidations of alcohols using molecular oxygen
DR Jensen, JS Pugsley, MS Sigman
Journal of the American Chemical Society 123 (30), 7475-7476, 2001
Enantioselective Heck arylations of acyclic alkenyl alcohols using a redox-relay strategy
EW Werner, TS Mei, AJ Burckle, MS Sigman
Science 338 (6113), 1455-1458, 2012
Enantioselective construction of remote quaternary stereocentres
TS Mei, HH Patel, MS Sigman
Nature 508 (7496), 340-344, 2014
Applications of ortho-Quinone Methide Intermediates in Catalysis and Asymmetric Synthesis
TP Pathak, MS Sigman
The Journal of organic chemistry 76 (22), 9210-9215, 2011
Recent advancements and challenges of palladium II-catalyzed oxidation reactions with molecular oxygen as the sole oxidant
KM Gligorich, MS Sigman
Chemical communications, 3854-3867, 2009
Elucidating the significance of β-hydride elimination and the dynamic role of acid/base chemistry in a palladium-catalyzed aerobic oxidation of alcohols
JA Mueller, CP Goller, MS Sigman
Journal of the American Chemical Society 126 (31), 9724-9734, 2004
Palladium catalysts for aerobic oxidative kinetic resolution of secondary alcohols based on mechanistic insight
DR Jensen, MS Sigman
Organic letters 5 (1), 63-65, 2003
Synthesis and preliminary biological studies of 3-substituted indoles accessed by a palladium-catalyzed enantioselective alkene difunctionalization reaction
TP Pathak, KM Gligorich, BE Welm, MS Sigman
Journal of the American Chemical Society 132 (23), 7870-7871, 2010
The development of multidimensional analysis tools for asymmetric catalysis and beyond
MS Sigman, KC Harper, EN Bess, A Milo
Accounts of chemical research 49 (6), 1292-1301, 2016
Palladium (II)-catalyzed enantioselective aerobic dialkoxylation of 2-propenyl phenols: a pronounced effect of copper additives on enantioselectivity
Y Zhang, MS Sigman
Journal of the American Chemical Society 129 (11), 3076-3077, 2007
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