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Jennifer Obligacion
Jennifer Obligacion
Associate Principal Scientist at Merck
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Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
JV Obligacion, PJ Chirik
Nature Reviews Chemistry 2 (5), 15-34, 2018
6592018
Bis (imino) pyridine cobalt-catalyzed alkene isomerization–hydroboration: a strategy for remote hydrofunctionalization with terminal selectivity
JV Obligacion, PJ Chirik
Journal of the American Chemical Society 135 (51), 19107-19110, 2013
3502013
Cobalt-catalyzed C–H borylation
JV Obligacion, SP Semproni, PJ Chirik
Journal of the American Chemical Society 136 (11), 4133-4136, 2014
3192014
Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity
JV Obligacion, JM Neely, AN Yazdani, I Pappas, PJ Chirik
Journal of the American Chemical Society 137 (18), 5855-5858, 2015
2562015
Highly selective bis (imino) pyridine iron-catalyzed alkene hydroboration
JV Obligacion, PJ Chirik
Organic letters 15 (11), 2680-2683, 2013
2192013
Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)–H Bonds
WN Palmer, JV Obligacion, I Pappas, PJ Chirik
Journal of the American Chemical Society 138 (3), 766-769, 2016
2042016
Cobalt-Catalyzed C(sp2)-H Borylation: Mechanistic Insights Inspire Catalyst Design
JV Obligacion, SP Semproni, I Pappas, PJ Chirik
Journal of the American Chemical Society 138 (33), 10645-10653, 2016
1302016
C(sp2)–H Borylation of Fluorinated Arenes Using an Air-Stable Cobalt Precatalyst: Electronically Enhanced Site Selectivity Enables Synthetic Opportunities
JV Obligacion, MJ Bezdek, PJ Chirik
Journal of the American Chemical Society 139 (7), 2825-2832, 2017
1142017
A kinase-cGAS cascade to synthesize a therapeutic STING activator
JA McIntosh, Z Liu, BM Andresen, NS Marzijarani, JC Moore, NM Marshall, ...
Nature 603 (7901), 439-444, 2022
582022
Mechanistic Studies of Cobalt-Catalyzed C(sp2)–H Borylation of Five-Membered Heteroarenes with Pinacolborane
JV Obligacion, PJ Chirik
ACS catalysis 7 (7), 4366-4371, 2017
582017
Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp2)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity
TP Pabst, JV Obligacion, É Rochette, I Pappas, PJ Chirik
Journal of the American Chemical Society 141 (38), 15378-15389, 2019
532019
Cobalt pincer complexes in catalytic C–H borylation: the pincer ligand flips rather than dearomatizes
H Li, JV Obligacion, PJ Chirik, MB Hall
ACS catalysis 8 (11), 10606-10618, 2018
372018
Diverse catalytic reactions for the stereoselective synthesis of cyclic dinucleotide MK-1454
T Benkovics, F Peng, EM Phillips, C An, RS Bade, CK Chung, ZEX Dance, ...
Journal of the American Chemical Society 144 (13), 5855-5863, 2022
332022
Recent advances in transition-metal-free aryl C–B bond formation
K Chen, L Wang, G Meng, P Li
Synthesis 49 (21), 4719-4730, 2017
252017
Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species
N Yoshikai
Synthesis 51 (01), 135-145, 2019
242019
Progress on iridium-catalyzed hydrosilylation of alkenes and alkynes
W Gao, S Ding
Synthesis 52 (23), 3549-3563, 2020
232020
Insights into Activation of Cobalt Pre‐Catalysts for C(sp2)−H Functionalization
JV Obligacion, H Zhong, PJ Chirik
Israel journal of chemistry 57 (10-11), 1032-1036, 2017
212017
PdII-porphyrin complexes–the first use as safer and efficient catalysts for miyaura borylation
KU Rao, K Venkateswarlu
Synlett 29 (08), 1055-1060, 2018
192018
Deoxygenative transformation of carbonyl and carboxyl compounds using gem-diborylalkanes
Y Hu, W Sun, C Liu
Synlett 30 (10), 1105-1110, 2019
152019
Investigation of lithium acetyl phosphate synthesis using process analytical technology
JP Smith, JV Obligacion, ZEX Dance, JP Lomont, NM Ralbovsky, X Bu, ...
Organic Process Research & Development 25 (6), 1402-1413, 2021
102021
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